To improve the safety of LIBs, various protection strategies based on self-actuating reaction control mechanisms (SRCMs) have been proposed, including redox shuttle, polymerizable monomer additive, potential-sensitive separator, thermal shutdown separator, positive-temperature-coefficient electrode, thermally polymerizable addi-tive, and reversible thermal phase transition electrolyte.
Once the potential rises up to the oxidation potential of electroactive polymer, the polymer transforms from an electronically insulating state to a highly conductive state, owing to the oxidative doping (i.e. p-doping), thus creating a current bypass to protect the battery from overcharging.
Among the three aforementioned SRCTs for overcharge protection of LIBs, polymerizable monomer additives can only provide irreversible protection, and therefore, future researches should focus on redox shuttles and potential-sensitive separators.
Polymerizable monomer additives are mostly aromatic compounds. Moli reported first that as an electrolyte additive, a small amount of biphenyl can significantly improve the overcharge safety of LIBs . Subsequently, Xiao et al. investigated the overcharge protection mechanism.
The battery protection circuit disconnects the battery from the load when a critical condition is observed, such as short circuit, undercharge, overcharge or overheating. Additionally, the battery protection circuit manages current rushing into and out of the battery, such as during pre-charge or hotswap turn on.
During normal charging and discharging, the electroactive polymers is in the intrinsic electronically insulating state and the polymer membrane functions as a conventional separator to conduct ions through its porous channels. When the battery is overcharged, its cathode potential undergoes a rapid rise.
What is Infineon battery protection?
For that, Infineon ofers a wide range of battery protection solutions that, under stressful conditions, increase lifetime and eficiency of lithium batteries. The battery protection circuit disconnects the battery from the load when a critical condition is observed, such as short circuit, undercharge, overcharge or overheating.